This quiz contains multiple-choice problems on autocatalytic reactions, selectivity and reactor yield.
Which of the following reactors is used for carrying out autocatalytic reactions?
An example of an autocatalytic reaction is
The formation reaction of ammonia
The decomposition reaction of hydrogen peroxide
The reaction of permanganate with oxalic acid
The oxidation of copper
If the area under the curve of -1/r{A} versus X{A} for a PFR used to carry out an autocatalytic reaction is 5(m^3.s/mol), the ratio of change in volume to molar feed rate is
5
10
15
20
Selectivity in parallel reactions is defined as the ratio of
Moles of desired product formed to the moles of undesired material formed
Moles of undesired product formed to the moles of desired material formed
Moles of product formed to the moles of reactant consumed
Moles of reactant consumed to the moles of product formed
The final concentration of product is related to the yield as
Final concentration = Yield × Reactant fed
Final concentration = Yield / Reactant fed
Final concentration = Yield × Reactant converted
Final concentration = Yield / Reactant fed
Consider two parallel reactions A→B and A→C. If B is desired product and reaction A→B is of positive order n1 and C is undesired product and reaction A→C is of negative order n2, increasing the concentration of A would
Decrease the desired product selectivity
Increase the desired product selectivity
Initially increase then decrease the desired product selectivity
Not affect the desired product selectivity
The autocatalyst in microbial fermentation reactions is
Organic feed
Microbes
Enzyme
Product chemical
Consider the parallel reactions A→B of order n1 and A→C of order n2. If B is the desired product, which of the following reactor/combination of reactors is used if n1 > n2?
CSTR
CSTR followed by bubbling bed reactor
PFR
CSTR followed by PFR
If the reactions A→B and A→C are represented as (-rA) = k1CA{3} and (-r{A}) = k2CA{6} of activation energies 130 J/mol and 150 J/mol respectively, which of the following is the right selection of process parameters to increase the selectivity of B?
CSTR, high temperature
PFR, high temperature
CSTR, low temperature
PFR, low temperature
For the parallel reaction A→B, represented as (-r{A}) = k1CA{5} and A→C represented as (-r{A}) = k2CA{3}, the ideal reactor preferred is
CSTR
CSTRs in parallel
CSTRs in series
PFR