Rate Laws and Stoichiometry

This quiz contains multiple-choice problems on rate laws, stoichiometry definitions, reaction order, elementary rate law, reversible reactions rate laws, constant–volume batch reaction systems, stoichiometry of batch and flow systems, batch and flow systems concentrations equations.

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It was Arrhenius who first suggested the temperature dependence of the rate constant. True or false?

True

False

Value of m to obtain the collision theory relation for temperature dependency of rate constant is

1

0

-1

0.5

The reaction rate of a bimolecular reaction at 300K is 10 times the reaction rate at 150K. Calculate the activation energy using collision theory.

4928 J/mol

5164 J/mol

3281 J/mol

1296 J/mol

Hydrogenation of oil is an example of a/an __ reactor.

Homogeneous

Heterogeneous

Autocatalytic

Insufficient data

Molecularity refers to an elementary reaction. True or false?

True

False

Molecularity is __ value, and order is __ value.

an integer, a fractional

a fractional, an integer

both fractional

both integers

Determine the relative rate for the given reaction:
2A + 9B → 7C + 4D

–rA = -9rB = 7rC = –4rD

–rA = -rB/9 = rC/7 = rD/4

–rA = -rB/9 = 7rC = 4rD

–rA = 9rB = -7rC = –4rD

The units of the rate constant of nth order is

time^(-1)

concentration^(n-1)

time^(-1) concentration^(1-n)

time^(-1) concentration^(n-1)

The reaction corresponding to stoichiometric equation is called

Non-elementary

Elementary

Heterogeneous

Homogeneous

The rate constant for a first-order reaction depends on

Pressure

Temperature

Concentration

Time

The overall reaction order for A + B → C + D is two. It implies that

The reaction may be non-elementary and molecularity is two

The reaction may be elementary and molecularity is two

The reaction is non-elementary and molecularity is two

The reaction is elementary and molecularity is two

Which theory is the basis for Arrhenius equation?

Collision theory

Kinetic theory of gases

Ideal gas law

Charles’s and Boyle’s law

The overall order of reaction for –rA = kC{A}^0.7C{B}^1.3 is

0

1

2

3

What are the units for constants 6 and 1670 of the reaction -r{A} = (1670[A][Po]/(6+C{A})).[kmol/ml.hr]?

kmol/mL

1/hr and 1/hr

kmol and kmol

Data insufficient

Quiz/Test Summary
Title: Rate Laws and Stoichiometry
Questions: 14
Contributed by:
Ivan